Use create replication definition to describe to Replication Server the characteristics of a table you want to replicate.
Execute create replication definition at the Replication Server that manages the source table database, or you can use the rs_send_repserver_cmd stored procedure with the create replication definition clause to execute replication definition change requests directly at the primary database.
A replication definition must include the name of the source data server and database.
create replication definition publishers with primary at TOKYO_DS.pubs2 (pub_id char(4), pub_name varchar(40), city varchar(20), state char(2)) primary key (pub_id)
See Replication Server Reference Manual > Replication Server Commands > create replication definition for complete command syntax and usage guidelines.