BACKUP always makes a full backup of the catalog store on the first archive device, and then backs up the data from the IQ store in parallel across all of the devices you specify. Blocks are not evenly distributed across archive media. You may have more on one device than others, depending on the processing speed of individual threads.
The distribution of backup data is important because sets of files must be restored in the order in which they were backed up. See “Restoring in the correct order” for more information.